Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono- or multi-substituted allenic esters.

Yuan-Liang Yang,Zhen Zhang,Xiao-Nan Zhang,De Wang,Yin Wei,Min Shi

CHEMICAL COMMUNICATIONS（2014）

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摘要

The reactions of cyclopropenones with nucleophiles (H2O ormethanol) could be catalyzed by nitrogen-containing Lewis bases or phosphoruscontaining Lewis bases, affording the corresponding mono-or multisubstituted allenic esters in moderate to excellent yields.

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