Density, Viscosity and Refraction Index of Aqueous Solutions of 7-Hydroxycoumarin and Ethanol or 1-Propanol at Temperatures from 293.15 to 313.15 K

Journal of Solution Chemistry(2013)

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Abstract
7-Hydroxycoumarin exhibits antioxidative, lipoxygenase inhibitive and anti-tumourigenic effects. Density and viscosity measurements have been carried out for the solutions of 7-hydroxycoumarin in mixture solvents of water and ethanol or 1-propanol at T = (293.15, 298.15, 303.15, 308.15 and 313.15) K. The measured data have been used to evaluate apparent molar volumes ( V ϕ ), limiting apparent molar volumes ( V_ϕ^0 ), viscosity B -coefficients of the Jones–Dole equation and variation of B with temperature (d B /d T ). The values of V_ϕ^0 and B -coefficients are positive and pass through their corresponding maxima at about 18 mol·kg −1 ethanol molality and 20 mol·kg −1 1-propanol molality, respectively. Besides, the values of V_ϕ^0 and B -coefficients decrease with increasing temperature. Molar refractive indices ( R D ) of the ternary solutions at the temperature of 298.15 K have also been determined from measured refractive indices ( n D ). There is an obvious increase of R D with increasing molality of the solvent. These parameters have been interpreted in terms of solute–solvent interactions and structure making/breaking ability of components in the aqueous solution. The temperature and concentration dependences of the weak interactions in the solution systems have also been discussed.
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Key words
7-Hydroxycoumarin,Density,Viscosity,Refractive index,Ethanol,1-Propanol
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