Solubility of Eu 2 (SeO 3 ) 3 and sorption of Eu(III) onto TiO 2 in the presence of Se(IV)

Journal of Radioanalytical and Nuclear Chemistry(2012)

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Abstract
Metal ions sorption can be significantly affected by the presence of other sorbates, especially of complexing ligands. In this study, the effect of Se(IV) on Eu(III) sorption onto TiO 2 at different pH and Eu(III) concentration was investigated. Se(IV) was found to enhance Eu(III) sorption as a function of Se(IV) concentration. Constant capacitance model was successfully used to interpret the sorption experimental data. The solubility product of Eu 2 (SeO 3 ) 3 at ambient temperature was investigated to highlight the sorption mechanism of ternary sorption system. The p K sp value of Eu 2 (SeO 3 ) 3 was found to be 31.51 ± 0.95.
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Key words
Eu(III),Se(IV),TiO2,Sorption,Solubility product,Eu2(SeO3)3
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