Correlation of crude oils and oil components from reservoirs and source rocks using carbon isotopic compositions of individual n-alkanes in the tazhong and tabei uplift of the tarim basin, China

Carbon isotopic compositions were determined by GC-IRMS for individual n-alkanes in crude oils and the free, adsorbed and inclusion oils recovered by sequential extraction from reservoir rocks in the Tazhong Uplift and Tahe oilfield in the Tabei Uplift of Tarim Basin as well as extracts of the Cambrian-Ordovician source rocks in the basin. The variations of the delta C-13 values of individual n-alkanes among the 15 oils from the Tazhong Uplift and among the 15 oils from the Triassic and Carboniferous sandstone reservoirs and the 21 oils from the Ordovician carbonate reservoirs in the Tahe oilfield demonstrate that these marine oils are derived from two end member source rocks. The major proportion of these marine oils is derived from the type A source rocks with low delta C-13 values while a minor proportion is derived from the type B source rocks with high delta C-13 values. Type A source rocks are within either the Cambrian-Lower Ordovician or the Middle-Upper Ordovician strata (not drilled so far) while type B source rocks are within the Cambrian-Lower Ordovician strata, as found in boreholes TD2 and Fang 1. In addition, the three oils from the Cretaceous sandstone reservoirs in the Tahe oilfield with exceptionally high Pr/Ph ratio and delta C-13 values of individual n-alkanes are derived, or mainly derived, from the Triassic-Jurassic terrigenous source rocks located in Quka Depression. The difference of the delta C-13 values of individual n-alkanes among the free, adsorbed and inclusion oils in the reservoir rocks and corresponding crude oils reflects source variation during the reservoir filling process. In general, the initial oil charge is derived from the type B source rocks with high delta C-13 values while the later oil charge is derived from the type A source rocks with low delta C-13 values. The delta C-13 values of individual n-alkanes do not simply correlate with the biomarker parameters for the marine oils in the Tazhong Uplift and Tahe oilfield, suggesting that molecular parameters alone are not adequate for reliable oil-source correlation for high maturity oils with complex mixing. (C) 2012 Elsevier Ltd. All rights reserved.