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Rhodium(i) complexes of unsymmetrical diphosphines: efficient and stable methanol carbonylation catalysts

Charles-Antoine Carraz,A. Guy Orpen,Dianne D. Ellis,Paul G. Pringle,Evert J. Ditzel,Glenn J. Sunley

CHEMICAL COMMUNICATIONS（2000）

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Abstract
Rhodium complexes of unsymmetrical diphosphines of the type Ph2PCH2CH2PAr2 are catalysts for the carbonylation of methanol; several features of the catalysis are reminiscent of iridium carbonylation catalysts.
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Key words
stable methanol carbonylation catalysts,unsymmetrical diphosphines,complexes
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