Octaisopropylchromocene: The First Chromocene With Gradual Low Spin High Spin-Transition

Helmut Sitzmann,Marion Sch�r,Elmar Dormann,Marc Kelemen

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE（1997）

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摘要

Octaisopropylchromocene (1) exists in a low spin state at very low temperatures and undergoes a gradual spin transition on warming up. At 300 K a high spin state with four unpaired electrons has been found for solid 1 by investigation of its magnetic properties.

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关键词

octaisopropylchromocene,magnetism,spin transition,metallocene

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