An ESR and electrochemical approach to the unusual reactivity of ferrocenoylsilanes with organometallic compounds
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY(2004)
摘要
ESR studies carried out during the reaction of ferrocenoylsilanes with Grignard reagents at low temperature led to the detection of the radical anions of the former compounds. Cyclic voltammetric experiments indicate that the observed radical anions are likely to originate through an inner-sphere electron transfer process. Different radical species were observed upon annealing, originating from destruction of the ferrocenyl moiety. Paramagnetic species were also detected on reacting ferrocenoylsilanes with LiAlH4. Copyright (C) 2004 John Wiley Sons, Ltd.
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关键词
ferrocenoylsilanes,Grignard reagents,electron spin resonance,ESR,cyclic voltammetry,single electron transfer,SET,radical anions
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