Synthesis, structure, and magnetic properties of a new binuclear Ni(II) complex supported by 1,4,8-triazacycloundecane
Inorganic Chemistry Communications(2008)
摘要
A new binuclear nickel(II) complex, [Ni2(tacud)2(μ-H2O)(μ-Cl)2]Cl2 (tacud=1,4,8-triazacycloundecane), is reported. In this complex, Ni(II) centers are bridged by two chloro and one aqua ligand while terminal positions are capped by tacud ligands. Magnetic studies reveal that the complex is weakly ferromagnetic.
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关键词
Macrocyclic ligand,Ni(II),Binuclear complex,X-ray crystallography,UV–vis spectroscopy,SQUID susceptometry
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