Oxidizing ability as the defining factor of reactivity of sulfated zirconia
CHEMICAL COMMUNICATIONS(1996)
摘要
Reaction of benzene with sulfated zirconia (SZ) is an oxidation to a surface phenyl ester (sulfite or sulfate) which forms phenol by hydrolysis, and a complex mixture of alkylbenzenes and polycyclic aromatics; a mechanism involving a one-electron transfer from benzene to SZ is proposed; oxidation of a fraction of substrate to alkyl surface esters which then ionize to carbocations is the origin of the high catalytic activity of SZ for alkane isomerization.
更多查看译文
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要