Acetato and formato copper(II) complexes with 4,4′-dimethyl-2,2′-bipyridine and 5,5′-dimethyl-2,2′-bipyridine: Synthesis, crystal structure, magnetic properties and EPR results. A new 1D polymeric water chain

Montserrat Barquín,Nerea Cocera,María J. González Garmendia,Liher Larrínaga,Elena Pinilla,José M. Seco,María R. Torres

Inorganica Chimica Acta（2010）

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摘要

The complexes [Cu(AcO)2(4,4′-Me2-2,2′-bipy)]·½H2O (1), [Cu(AcO)2(5,5′-Me2-2,2′-bipy)(H2O)] (2), [Cu(HCOO)(μ-HCOO)(4,4′-Me2-2,2′-bipy)]n·nH2O (3) and [Cu(HCOO)(μ-HCOO)(5,5′-Me2-2,2′-bipy)]n·2nH2O (4) were obtained and characterized.

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关键词

Copper(II),4,4′-Dimethyl-2,2′-bipyridine,5,5′-Dimethyl-2,2′-bipyridine,Hydrogen bonds,1D water chain

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