Preparation Of Nitrobenzaldehydes And Nitrophenyl Ketones By Electrophilic Amination Of Nitrobenzyl Aryl Sulfones

Jens-Peter Wulf,Krzysztof Sienkiewicz,Mieczyslaw Mąkosza, Ernst Schmitz

LIEBIGS ANNALEN DER CHEMIE（1991）

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摘要

Nitrobenzyl Aryl Sulfones 1a - g react with 3,3-pentamethylene-oxaziridine (2) with incorporation of an NH group into the benzylic position, followed by cleavage to nitrobenzaldehydes 4a - d and nitrophenyl ketones 4e - g, respectively.

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关键词

OXAZIRIDINE, 3,3-PENTAMETHYLENE-OXAZIRIDINE, SULFONES, ELECTROPHILIC AMINATION OF, NITROBENZALDEHYDES, NITROPHENYL KETONES

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