The chromous chloride promoted addition of N-haloamides to olefins. IV. Mechanistic aspects
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE(1977)
摘要
A discussion on the mechanism of the chromous chloride promoted addition of N-haloamides to olefins is presented on the basis of the results already reported and some additional evidence. The mechanism proposed involves a radical chain addition in which the N-haloamide acts as the transfer agent, the termination steps being chromium(II) reduction of the amido radical and chromium(II) reduction of the intermediate adduct radical. The addition of N-chloro- and N-bromoacetamide to norbornadiene is described. The use of chromous chloride to initiate the reaction of N-chloropiperidine with ethyl vinyl ether and cyclohexene led to low yields of addition.
更多查看译文
关键词
chromous chloride,olefins
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要