Analysis Of Components Depth Profile At The Interface Of Ti6242 Alloy And Tini Coatings After High Temperature Oxidation In Air
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 7, NO 11-12(2010)
摘要
We have analyzed the interfacial elemental depth profile evolution after high temperature isothermal oxidation of NiTi coatings deposited by dynamic ion mixing on a Ti6242 alloy (Ti-6Al-2Sn-4Zr-2Mo). NiTi coatings (thickness 0.4 mu m) were deposited at room temperature (RT) by ion beam sputtering. High temperature isothermal oxidation tests in 1 atm flowing synthetic air (80% N-2, 20% O-2) have been conducted at 500 degrees C and 600 degrees C during 100 hours. We have observed a non-monotonous depth distribution of nickel in GDOES depth profiles after oxidation of TiNi/Ti6242: nickel segregates to the surface of TiNi coating and to the interface between TiNi coating and Ti6242 alloy. We propose a kinetic model based on rate equations for analyzing the depth profile. This model includes microprocesses taking place during oxidation in air such as: adsorption of nitrogen and oxygen, diffusion of components through the film and interface, formation of chemical compounds. It is shown by modeling that non-monotonous depth profile of nickel occurs because nickel from TiNi coating is forming a nickel oxide compound when oxygen atoms reach the film/alloy interface. XRD analysis confirms the presence of nickel oxide in the TiNi/Ti6242 interface after oxidation at both temperatures 500 degrees and 600 degrees C. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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关键词
TiNi alloys,oxidation,interface structure,depth profiling
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