Metallaborane reaction chemistry. Part 12. Some interactions of acetylenes and isocyanides with selected metallaboranes

Jonathan Bould,Mark Bown,Richard J. Coldicott,Evert J. Ditzel,Norman N. Greenwood,Ian Macpherson,Peter MacKinnon,Mark Thornton-Pett,John D. Kennedy

Journal of Organometallic Chemistry（2005）

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摘要

An overview of reactions of acetylenes and isocyanides with metallaboranes of general type {MB9H13} and {MB8H12} is presented. Reductions, oligomerisations, reductive oligomerisations, and complete or partial cluster-incorporation of the unsaturated species have been observed.

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关键词

Borane cluster,Metallaboranes,Cluster Aufbau,Cluster expansion,Cluster dismantling,Platinum, ruthenium, iridium and rhodium complexes of boranes and heteroboranes,X-ray crystal and molecular structures,Metallaborane reaction chemistry,Platinaboranes,Iridaboranes,Ruthenaboranes,Rhodaboranes

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