Preparation of Non‐Substituted Metal Phthalocyanines at Low Temperature Using Activated Rieke Zinc and Magnesium

B. Kharisov, L. Garza‐Rodríguez,H. Leija Gutiérrez,U. Ortiz Méndez, R. García Caballero,A. Tsivadze

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY（2012）

Cited 8|Views4

No score

Abstract

Synthesis of non-substituted metal phthalocyaninates starting from phthalonitrile in various alcohols in presence of chemically activated Rieke zinc and magnesium in three forms (ordinary magnesium turnings, activated Rieke magnesium and complex Mg(anthracene)center dot 3THF) at low temperatures (20-50 degrees C) is described. It is shown that the presence of active elemental metal causes a rapid PcM formation in low-weight alcohols.

Translated text

Key words

zinc and magnesium phthalocyaninate,Rieke metals,synthesis at low temperature

AI Read Science

Must-Reading Tree

Example

Generate MRT to find the research sequence of this paper

Chat Paper

Summary is being generated by the instructions you defined