SIMPLE METHOD FOR THE SYNTHESIS OF STANNOLE DIANION

Masaichi Saito,Ryuta Haga,Michikazu Yoshioka

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS（2010）

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摘要

Reduction of 1-t-butyl-1,2,3,4,5-pentaphenylstannole by lithium gave the stannole dianion. Reduction of the bi(1,1-stannole) having a t-butyl group on the tin by lithium also gave the stannole dianion, the formation of which was evidenced by spectral analysis and chemical trapping reaction.

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关键词

1-t-Butyl-1-phenylstannole,bi(1,1-stannole),reduction,stannole dianion

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