The Determination Of The Stereochemistry Of Epoxides Located At The 5,6-Positions Of Decalinic Systems: An Empirical Method Based On C-13 Nmr Chemical Shifts
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE(2002)
摘要
The C-13 NMR spectra of a series of 5,6-epoxides in decalinic systems were studied. The interpretation of the chemical shifts allowed us to formulate an empirical rule to predict the epoxide stereochemistry. A discussion of the scope and limitations of this method and its extension to larger carbon skeletons is also presented.
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关键词
epoxide stereochemistry,C-13 NMR,NMR,decalinic systems,oxiranes
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