Optical Behaviors Of Conjugated-Chain Compounds Containing Benzene And Furan Units

Thirteen conjugated-chain compounds which contain benzene and furan units were prepared, their optical behaviors, including UV-vis absorption coefficient (epsilon), absorption wavelengths (lambda(a)) fluorescence emission wavelengths and quantum yields (0) were measured. Meanwhile, their LUMO and HOMO energy were determined by cyclic voltammetry and their second-order polarizations (beta(xxx)) values were determined by solvatochromic method, respectively. The results showed that this kind of compounds possess a shorter lambda(a) (320-365 nm) and performance a higher (P values, especially for 2aa, 2ab, 2ac and 2bb, their Phi values are all more than 90%. These compounds, except 2db, showed a higher beta(xxx) values in DMSO, especially for 2dc (75.77 x 10(-30) m(5) C-1) and 2dd (83.32 x 10(-30) m(5) C-1), than that 10-methyl-acri done (6.578 x 10(-30) m(5) C-1) or 10-benzylacridone (6.845 x 10(-30) m(5) C-1) in DMSO did, and second harmonic generation value of 10-methylacridone and 10-benzylacridone in powder are, respectively, 1.381 and 1.861 times of that value of urea. The beta(xxx) values and Phi values determined for these compounds in this work were lower than these values which were desired in the original work, this phenomena was explained from their molecular structures. This work confirmed that as these compounds performance shorter lambda(a) and higher Phi values, they could be good blue-color optical materials for some fields, such as OLED materials, two-photo absorption materials, fluorescent dyes. (c) 2006 Elsevier B.V. All rights reserved.