Total synthesis ofdl-9(11)-dehydrotestosterone anddl-testosterone

Dwijen Banerjee,K M Damodaran,P S N Murthy,V Paul

Proceedings of the Indian Academy of Sciences - Section A, Chemical Sciences（1978）

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摘要

17β-Hydroxy-des-A-androst-9-en-5-one (II, R=OH), prepared fromtrans-1β-hydroxy-8-methyl-4, 5-(3′-methyl-4′-methoxybenzo)-hydrindane (I, R=CH3)′, has been converted intodl-9(II)-dehydrotestosterone (IV, R=OH) anddl-testosterone (IX) in very short sequences of steps, albeit in poor yields.

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关键词

Synthesis, steroids, ring A formation

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