Selective decarbonylation by a pincer PCP-rhodium(I) complex
Inorganica Chimica Acta(2008)
Abstract
A highly selective stoichiometric decarbonylation reaction for alkylformates and alkynyl aldehydes by a rhodium–dinitrogen complex at room temperature is rationalized predominantly by a steric effect, consistent with the results of an X-ray crystallographic study and density functional theory modeling.
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Key words
Selective decarbonylation,Steric effect,Pincer,Rhodium
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