Proton Transfer and Thermochromism of the Crystals of the Picric Acid CT Complexe

Masashi Tanaka,Yuichi Yamazaki,Hiroshi Suzuki,Hisahiro Hayashi

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS（1996）

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摘要

The picric acid forced picrate salts or charge-transfer (CT) complexes with hexamethylbenzene(HMB). 2-iodoaniline(IAn). and 1-aminoanthracene(AAt). The crystals of these salts or complexes shored the thermochromism upon heating. The mechanism of the thermochromism ras discussed by the temperature-variable FTIR absorption spectral data and the DSC thermal analysis data together with the results of the a-ray crystal structure analysis.

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