[Mn(tacn)]2Mo(CN)7·5H2O: a 90K ferromagnet

Physica B: Condensed Matter（2002）

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摘要

We report the synthesis of the compound [Mn(tacn)]2[Mo(CN)7]·5H2O, another addition to the family of MnMo-heptacyanates. It is obtained by capping the Mn(II) with the ligand ‘tacn’ (triazacyclononane) and reacting it with the [MoIII(CN)7]4− precursor. It exhibits ferromagnetic behavior below 90K.

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关键词

Prussian blue analogue,Heptacyanate,Molecular ferromagnet

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