Palladium-mediated fragmentation of meta photocycloadducts using carbon based electrophiles. Part 1
Tetrahedron(2006)
摘要
Substituted benzene derived meta photocycloadducts have been shown to undergo a fragmentation/arylation reaction under Heck reaction conditions to give bridged bicyclo[3.2.1] compounds in a highly atom-efficient manner. When an anisole derived meta photocycloadduct is used, a bridgehead ketone is generated. However, if an alkylbenzene derived meta photocycloadduct is used, a bridgehead alkene is formed. This strategy has been used to create novel enol ether and transient allyl silane compounds.
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关键词
Photoaddition,Palladium,Heck reaction,Tandem reaction,Atom efficiency,Allylsilane formation
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