Superconductivity in layered YB2C2
Journal of Physics Conference Series(2009)
摘要
Superconductivity in the layered yttrium diboride dicarbide, YB2C2, has been revisited by means of specific heat, magnetic susceptibility and resistivity measurements down to 50 mK revealing a bulk superconducting transition at 1.0 K. Analysing the low temperature specific heat we obtain a Sommerfeld coefficient of the normal state electonic contribution, gamma = 3.1(1) mJ/mol K-2, and a Debye temperature, Theta(LT)(D) = 680(10) K. The specific heat anomaly at T-C, Delta C similar or equal to 4.5 mJ/mol K, thus, yields a thermodynamic ratio Delta C/gamma T-C similar or equal to 1.4 in close agreement with the BCS value. For polycrystalline (YB2C2)-B-11 prepared by inductive melting we observe a pronounced resistive anomaly near 3.6K which, however, corresponds to a rather spurious specific heat anomaly and is thus attributed to traces of YC2 present in this sample.
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关键词
superconductivity,layered yb<sub>2</sub>c<sub>2</sub>
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