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Formate-induced destabilization of the Cu(110) surface

S.J. Harrington,K.V. Kilway,D.-M. Zhu,J.M. Phillips,F.M. Leibsle

Surface Science（2006）

Cited 14|Views14
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Abstract
Scanning tunneling microscopy (STM) images show that adsorbed formate has a profound affect on the step edges of Cu(110) surfaces at room temperature. For low exposures, the presence of formate enhances step fluctuations as confirmed by a correlation function analysis. For formate coverages approaching 0.5 monolayers, drastic restructuring of step edges is observed. Quantum chemical calculations help to explain this behavior.
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Key words
Scanning tunneling microscopy,Copper,Formate,Surface chemical reactions,Surface roughening,Semiempirical calculations
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