Exploitation of the photochromic nitroprusside anion [ FeNO(CN)₅]^2-as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

R P Shibaeva,Salavat S Khasanov,Leokadiya V Zorina,Sergey V Simonov,I. Shevyakova,L A Kushch,L I Buravov,E B Yagubskii,S. Baudron,Cecile Meziere,Patrick Batail,Enric Canadell,Junzaburo Yamada

JOURNAL DE PHYSIQUE IV（2004）

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摘要

The radical cation salts based on BDH-TTP and the mono- and diamide functionalized derivatives of EDT-TTF with the double charged nitroprusside anion [FeNO(CN)(5)](2-) (NP): kappa-(BDH-TTP)(4)[NP]C6H5NO2 (1), kappa-(BDH-TTP)(4)[NP] (2), (BDH-TTP)(2)[NP] (3), alpha-[EDT-TTF-CONH2](4)[NP] (4), beta-[EDT-TTF-(CONH2)(2)](2)[NP](0.5)(C6H5NO2)(0.5) (5) have been synthesized. The crystal structures and transport properties of 1-5, as well as electronic band structures of 1 and 2 have been studied.

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organic conductors based on radical cation salts,X-ray and band structure,conductivity

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Exploitation of the photochromic nitroprusside anion [ FeNO(CN)5]2-as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

Exploitation of the photochromic nitroprusside anion [ FeNO(CN)₅]^2-as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF