Biradicaloid character of phenalenyl-based aromatic compounds with a small HOMO–LUMO gap

Polyhedron（2005）

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摘要

Theoretical and experimental considerations for the biradicaloid character of three phenalenyl-based compounds are described.

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关键词

Phenalenyl,Small HOMO–LUMO gap,Amphoteric redox,Singlet biradical,Triplet biradical,Short non-bonding contact

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