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Chiral enamide. Part 1: Epoxidations of chiral enamides. A viable approach to chiral nitrogen stabilized oxyallyl cations in [4+3] cycloadditions

Hui Xiong,Richard P. Hsung,Lichun Shen,Juliet M. Hahn

Tetrahedron Letters（2002）

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Abstract
The first study of stereoselective epoxidations of chiral enamides is described here. Its potential in the synthesis of chiral α-keto aminals as a viable approach to nitrogen stabilized oxyallyl cations in stereoselective [4+3] cycloadditions is also illustrated.
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nitrogen
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