Unusual interaction of perfluoroaromatic organozinc compounds with benzoyl chloride and DMF

Andrey S. Vinogradov,Vyacheslav I. Krasnov,Vyacheslav E. Platonov

Mendeleev Communications（2008）

引用 7|浏览15

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摘要

The organozinc compounds obtained from chloropentafluorobenzene and octafluorotoluene in reactions with benzoyl chloride and DMF form N,N -dimethylbis(perfluoroaryl)methylamines; the addition of CuCl changes the direction of reaction towards the formation of corresponding polyfluoroaromatic ketones.

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