The Base-Catalyzed H/D-Exchange of Anisole Moiety of Ruthenium Complex in Cooperation with Demethylation by Hydroxide Anion in Methanol d4.

Masaru Kimura,Mitsunobu Morita,Hideo Mitani,Hideki Okamoto,Kyosuke Satake,Shiro Morosawa

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN（1992）

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摘要

[Ru(eta5-C5H5)(eta6-arene A)]BF4 (arene A=nitrobenzene, m- or p-nitrotoluene, anisole, phenetole, m- or p-methylanisole) were quantitatively converted to pure [Ru(eta5-C5H5)(-eta6-arene B)]BF4 (arene B=phenoxido-2d, m- or p-monodeuterated methylphenoxido) in the presence of excess KOH in CD3OD, whereas [Ru(eta5-C5H5)(eta6-anisole)] BF4 was quantitatively obtained by treatment [Ru(eta5-C5H5)(eta6-nitrobenzene)] BF4 with 1 equivalent KOH or CH3OK.

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