Evolution of the dynamic susceptibility of simple glass formers in the strongly supercooled regime

S Adichtchev,T Blochowicz,C Gainaru,V N Novikov, E A R ssler,C Tschirwitz

JOURNAL OF PHYSICS-CONDENSED MATTER(2003)

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摘要
We discuss dielectric and light scattering susceptibility spectra of simple glass formers at temperatures above as well as below the critical temperature of the mode coupling theory (MCT). Close to T-g the systems are characterized by the presence of a pronounced excess wing (type A glass formers). The data are analysed within a phenomenological approach, on the one hand, and within MCT, on the other. Among other work we present a complete interpolation of the dielectric data for glycerol (Lunkenheimer et al 2000 Contemp. Phys. 41 15). The crossover temperature T-x, defined by the emergence of the excess wing upon cooling, is extracted from the phenomenological analysis and found to agree well with the critical temperature T-c, extracted from the MCT analysis at high temperatures. Below T-x the evolution of the susceptibility is characterized by a universal appearance of the excess wing. No difference is observed for the non-fragile system with respect to fragile glass formers provided that the wing parameters are studied as a function of the correlation time tau(alpha). Finally, a generalized scaling for the susceptibility minimum is proposed which is a phenomenological extension of that of MCT but now also includes the data below T-c.
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light scattering
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