Easy Preparation and Prominent Gelation of New Gelator Based on L-Lysine.

CHEMISTRY LETTERS(2000)

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摘要
A new prominent gelator 1, N-epsilon-lauroyl-N-alpha-stearylamino-carbonyl-L-lysine ethyl ester was effortlessly prepared by esterification of N-epsilon-lauroyl-L-lysine and addition of n-octadecyl iso cyanate in a total yield of 89%. Gelator 1 was capable of gelling up a wide variety of organic fluids. A comparison of the gelation ability of structurally related compounds clarified that not only the introduction of long-chain alkyl but also more importantly the ureylene segment connecting the alpha-amino group and the alkyl chain are required for effective gelation.
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