The Charge Of Solid-Liquid Interfaces Measured By X-Ray Standing Waves And Streaming Current
Chemphyschem : a European journal of chemical physics and physical chemistry(2010)
摘要
Measurements of ion distributions at a charged solid liquid interface using X-ray standing waves (XSW) are presented. High energy synchrotron radiation (17.48 keV) is used to produce an XSW pattern inside a thin water film on a silicon wafer. The liquid phase is an aqueous solution containing Br and Rb ions. The surface charge is adjusted by titration. Measurements are performed over a pH range from 2.2-9, using the native Si oxide layer and functional (amine) groups as surface charge. The Debye length, indicating the extension of the diffuse layer, could be measured with values varying between 1-4 nm. For functionalized wafers, the pH dependent change from attraction to repulsion of an ion species could be detected, indicating the isoelectric point. In combination with the measurement of the streaming current, the surface charge of the sample could be quantified.
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关键词
interfacial charge,solid/liquid interfaces,surface analysis,surface functionalization,X-ray spectrometry
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