A Reinvestigation of the Didemnaketals from the Palauan Ascidian Didemnum sp
NATURAL PRODUCT LETTERS(2006)
Abstract
Reinvestigation of the ascidian Didemnum sp. from Palau revealed that the previously reported metabolites, didemnaketals A (1) and B (2), are artifacts formed as a result of prolonged storage of the ascidian in methanol. Fresh extracts gave a single terpenoid, didemnaketal C (3), which on methanolysis yielded didemnaketal B (2).
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Key words
ascidian,Didemnum sp,heptaprenoid,didemnaketals A-C
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