The reactivity of metallated nitrenium ions studied by FT-ICR

Michael J. Yurkovich,Penggao Duan,Ryan C. Shea,Michael A. Watkins,Sarah M. Mandell,Eric M. Tippmann,Sen Jason Li,Matthew S. Platz,Hilkka I. Kenttämaa

International Journal of Mass Spectrometry（2009）

引用 5|浏览8

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摘要

Two metallated nitrenium ions show drastically different reactivity. While the Mg-nitrenium ion reacts by radical mechanisms, the Cu-nitrenium ion follows non-radical pathways.

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关键词

Nitrenium ion,Ion-molecule reaction,Magnesium cation,Copper cation,FT-ICR

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