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环氧树脂改性有机硅聚合物的合成与应用性能研究

Fine and Specialty Chemicals(2011)

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Abstract
正硅酸乙酯水解可得有机硅聚合物,但产物分子量不高,成膜性差。用环氧树脂对其改性,制得物的涂膜成膜性优良,且大大缩短固化时间。研究了水解温度与时间,催化剂种类,溶剂用量和环氧树脂用量、反应温度与时间对改性物的影响。结果表明,水解温度50℃,时间3h,硫酸催化,乙醇用量35%,环氧树脂用量20%~50%,反应温度50℃,反应时间1h,涂膜性能优良。
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Key words
modification,epoxy resins,tetraethyl orthosilicate
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