Isolation, Total Synthesis, and Relative Stereochemistry of a Dihydrofurocoumarin fromDorstenia contrajerva
JOURNAL OF NATURAL PRODUCTS(1998)
摘要
The roots of Dorstenia contrajerua afforded the dihydrofurocoumarin 1b whose identity was determined from NMR spectral data of the derived acetate 7b combined with the total syntheses of 1a and 1b, which were carried out in five steps with 19% overall yield, starting from 2,3-dihydro-2-isopropenyl-6-methoxybenzofuran (2). The relative stereochemistry of 7b was determined from a single-crystal X-ray diffraction study as(2S*,1'S*)-2,3-dihydro-2-(1'-hydroxy- l'-acetyloxymethylethyl)-7H-furo[3,2g][1]benzopyran-7-one.
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关键词
total synthesis
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