Investigation of the chloride ion transport mechanism in unsaturated concrete considering the nonlinear seepage effect

In this paper, the mechanism of chloride ion transport in unsaturated concrete considering the nonlinear seepage effect is investigated by indoor experiments and analytical modelling. The concrete sheet imbibition test is used to reveal the nonlinear characters of seepage including water convection and moisture capillary within the unsaturated concrete in case of various water-binder ratios. For modelling purpose, an exponential function is introduced to mathematically depict the nonlinear relation between the specific discharge and hydraulic gradient during both water convection and moisture capillary processes. Based on such nonlinear seepage models, new mathematical models are proposed for the problem of chloride invasion within the reinforced concrete structure. The solution for the mathematical model of chloride transport is resolved by Laplace transform and finite difference method, of which acceptability is verified by the comparison with the results from chloride ion invasion test. The result indicates that, compared with linear seepage law, the use of the proposed nonlinear seepage solution is preferred to depict the saturation-relative humidity curves from concrete sheet imbibition test. The consideration of nonlinear seepage can result in a slower chloride transport rate, which further makes a later flow start-up time and a smaller free chloride iron concentration within the concrete. Such effect can be enhanced with the increase of nonlinear flow degree. The paper provides an effective solution to evaluate the chloride invasion within the unsaturated concrete.