A NEW TYPE COPPER(II)-GADOLINIUM(III) COMPLEX OF PHENOL-BASED SIDE-OFF TYPE DINUCLEATING LIGAND CONTAINING FULLY SATURATED AMINO NITROGENS AS COORDINATING ATOMS

Kazuhiro Manseki,Hiroshi Sakiyama,Masatomi Sakamoto,Yuzo Nishida,Hiromichi Aono,Yoshihiko Sadaoka,Masaaki Ohba,Hisashi Okawa

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY（2011）

Cited 5|Views5

No score

Abstract

The copper(II)-gadolinium(III) complex of a phenol-based side-off type di-nucleating ligand was newly synthesized, using N, N'-dimethyl-N,N'-ethylene-di(5-bromo-3-formyl-2-hydroxybenzylamine). Structural analysis revealed that one of the two formyl groups is converted into a hemiacetal group and the two dinuclear CuGd units are bridged by the alcoholic oxygens of acetal groups of each unit to construct the tetranuclear (CuGd)(2) core.

Translated text

Key words

copper,nitrogen,structure analysis

AI Read Science

Must-Reading Tree

Example

Generate MRT to find the research sequence of this paper

Chat Paper

Summary is being generated by the instructions you defined