Towards “designer” surfaces: functionalisation of self-assembled monolayer (SAM) on colloidal gold by alkene metathesisElectronic supplementary information (ESI) available: experimental data and Figs S1–S14. See http://www.rsc.org/suppdata/cc/b3/b300833a/Part of this work was presented at the First International Conference on Bio-Organometallic Chemistry, July 2002, Paris. Abstract no PB5.

Debasis Samanta,Nicolas Faure,Francis Rondelez,Amitabha Sarkar

CHEMICAL COMMUNICATIONS（2003）

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摘要

A variety of groups like a Fischer carbene complex, an N-hydroxysuccinimide or a ferrocene derivative have been grafted by ruthenium-catalyzed cross-metathesis reaction with terminal alkene groups on monolayer-protected gold clusters as a mild and convenient strategy to anchor functional molecules.

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关键词

colloidal gold,self assembled monolayer

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