A metallocarbenoid approach to the formation of spirocyclic ammonium ylides leading to the preparation of medium-sized azacane rings
TETRAHEDRON LETTERS(1996)
Abstract
A novel approach to azacyclooctene and azacyclononene containing substrates has been achieved via the intermediacy of a spirocyclic ammonium ylide derived from the diazodecomposition of a tethered alpha-diazoester moiety.
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Key words
spirocyclic ammonium,metallocarbenoid approach,medium-sized
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