Action des trialkylsilanes sur les aldehydes aliphatiques : I. Etude des evolutions en presence d'un catalyseur au nickel en l'absence de solvant
Journal of Organometallic Chemistry(1975)
摘要
Two competing reactions ensue when trialkylsilanes HSiR′3 are treated with aliphatic aldehydes RCHO in the absence of a solvent and using a nickel catalyst (obtained by the treatment of anhydrous NiCl2 with a trialkylsilane); one gives an alcoxysilane RCH2OSiR′3, the other an ether oxide (RCH2)2O and a siloxane (R′3Si)2O. By variation of the reaction conditions, either reaction can be made exclusive. Reaction mechanisms are proposed.
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关键词
nickel
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