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New Ditopic Ligands Containing 2,2′:6′,2′′-Terpyridine and a Rigid U-/S-Shaped Terpyridine

Johanna Hummel,Andreas Winter,Anja Baumgaertel,Nikolaus Risch,Ulrich Schubert

SYNLETT（2010）

Cited 3|Views9
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Abstract
The modular approaches towards 2,2':6',2 "-terpyridines and U-/S-shaped terpyridines are combined to yield a new family of ditopic ligands. Functionalized Krohnke-type terpyridines were used as key building blocks for the construction of hetero-bis(terpyridine)s. The described compounds might serve as new templates for the self-assembly towards new metallosupramolecular functional materials.
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Key words
cross-coupling,iminium salts,Mannich reaction,supramolecular chemistry,terpyridines
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