30 years of research in thermal analysis and calorimetry
Journal of Thermal Analysis and Calorimetry(2007)
摘要
The research in thermal analysis and calorimetry, conducted by the author over the period 1964 to 1993, is summarised and
concisely reviewed. The major investigations have focussed on thermal analysis studies of coordination compounds, particularly
the metal dithiocarbamate complexes. A significant solution calorimetric study of some metal dithiocarbamate complexes has
also been undertaken. DSC has been applied to determine the sublimation enthalpies of many metal dithiocarbamate and metal
pentane-2,4-dionate complexes and solution calorimetry has been applied to study the thermochemistry of the latter group of
complexes. Thermal analysis investigations of several inorganic molten salt systems have been initiated. Thermometric titrimetry
has been applied to study metal-macrocyclic ligand systems in aqueous media and particularly those systems of environmental
significance. Temperature calibration standards for TMA have been proposed and TMA has been applied to study the mechanical
properties of several common inorganic compounds. DTA has been applied to study a wide variety of phenols and has subsequently
been applied as an analytical technique to determine the components of solid state phenol mixtures. Thermometric titrimetry
has been applied to determine the phenolic content of wines. A comprehensive thermal analysis study of Australian brown coal
has been undertaken, involving the DSC determination of coal specific energy, a TG/DTA study of the coal pyrolysis and combustion
processes and a TG/DTA and EGA study of the cation catalytic effect on the coal pyrolysis process. Thermal analysis and calorimetric
techniques have been extensively publicised and promoted by the publication of specialist reviews, the presentation of symposia
review papers and the oral presentation of short courses, particularly in the SE Asian region. This review essentially reveals
the diversity of possible application of thermal analysis and calorimetric techniques and the primary significance of thermodynamic
data in the fundamental rationalisation of chemical phenomena.
更多查看译文
关键词
thermal analysis,personal research review,calorimetry,thermodynamics
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要