A moderate and efficient method for oxidation of ethylbenzene with hydrogen peroxide catalyzed by 8-quinolinolato manganese(III) complexes
Journal of Molecular Catalysis A: Chemical(2010)
摘要
The oxidation of ethylbenzene with 30% aqueous hydrogen peroxide (H2O2) in an acetone–water medium at 30°C was investigated using hexadentate 8-quinolinolato manganese(III) complexes (Q3MnIII) as catalysts. The results indicated that the Q3MnIII complexes, with ammonium acetate and acetic acid as additives, selectively catalyzed the side chain oxidation of ethylbenzene at secondary carbon atoms, affording acetophenone as a major product. Among the Q3MnIII complexes examined, the 5,7-dibrominated Q3MnIII catalyst was the most active, and provided the ethylbenzene conversion of 26.1% and the oxidation yield of 65% under the optimum conditions. The influence of various parameters on the reaction was checked in detail. Based on the UV–vis spectra, a free radical mechanism for the Q3MnIII catalytic system was also proposed.
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关键词
Ethylbenzene,Catalysis,Hydrogen peroxide,8-Quinolinolato Mn(III) complexes,Selective oxidation
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