On the Stereochemistry of Vincetene

David Jirovsky,Andreas Sellmer, Pierre Guiswe,Karel Lemr,Wolfgang Wiegrebe

Monatshefte für Chemie / Chemical Monthly（2001）

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摘要

Summary. The absolute configuration of the centre of asymmetry in the side chain of the alkaloid vincetene ( 1 ) was determined by ozonolysis and subsequent unequivocal transformations affording the ( S )-enantiomer of 1,2-propanediyl dibenzoate ( 4 ).

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关键词

Keywords. Alkaloids,Vincetene,Absolute configuration,Ozonolysis,1,2-Propanediyl dibenzoate,Chiral resolution.

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