Photochemical rearrangement of mortonin C
TETRAHEDRON(1984)
Abstract
Irradiation of Mortonin C ( 1a ) produced the photoproducts 4a and 8a as a result of a photochemically induced ring contraction of the tetrahydro-oxepine nucleus. The structure and stereochemistry of 4a and 8a were proved by chemical degradation and spectroscopic analysis.
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