Transformation Of Sugar Into Glycols On A 5-Percent Ru/C Catalyst

P. Müller,P. Rimmelin,J.P. Hindermann,R. Kieffer,A. Kiennemann,J. Carré

HETEROGENEOUS CATALYSIS AND FINE CHEMICALS II（1991）

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摘要

Saccharose hydrogenolysis was performed in a slurry type reactor in presence of a 5% Ru/carbon catalyst. Modification of pH during the reaction can increase the yield of 1, 2-propane diol and glycerol noticeably. An adsorbed complex is proposed to account for the difference in selectivity for various C 5 and C 6 sugars.

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