Synthesis, spectroscopic properties and electrochemistry of Rh2(ap)4(R) where R = CH3 or C6H5 and ap = 2-anilinopyridinate anion

John L. Bear,Baocheng Han,Yulan Li,Siyabonga Ngubane,Eric Van Caemelbecke,Karl M. Kadish

Polyhedron（2009）

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摘要

Two sigma-bonded Rh25+ complexes, Rh2(ap)4(C6H5) and Rh2(ap)4(CH3), where ap=2-anilinopyridinate anion were synthesized and examined as to their electrochemical and spectroscopic properties in nonaqueous media.

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关键词

Dirhodium,σ-bonded,Electrochemistry,Spectroelectrochemistry,X-ray structure,ESR

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