Ring-expansion of 5-methylene-thiazolidine-2-thione with hydrazine

Saifidin Safarov,Elmurod Pulatov,Muhamacho Amadovich Kukaniev,Heinz Kolshorn,Herbert Meier

JOURNAL OF HETEROCYCLIC CHEMISTRY（2009）

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摘要

The treatment of 5-methylene-thiazolidine-2-thione with hydrazine hydrate in boiling dioxane leads in a novel type of ring-expansion reaction to 6-methyl-1,2,4-triazine-3-thione.

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